If your engine is overheating you are not getting cooler water into the engine so your problems are esentially limited. It would be good to know how quick it overheats and unde what conditions. What is the state of the engine- both modified and tuned alterations.
1. Radiator blocked or fan not working (I think you said you turned the thermos on full time so radiator is next option)
2. Water pump not working - impellor not moving with the pulley (yes it does happen on new pumps even) or
3. Thermostat not working - try remove it or alter the old one to allow some flow and take for a drive (definitely not a long term fix)
This assumes nothing else has changed from when it was fine, but if it has then that is the first thing to change back to the previous setting. Once this is done and problem still exists then work through the these possible faults.
If you think the head gasket is blown (in your case communicating with the cooling system) then my previous suggestion of using the screwdrivers into the combustion chamber should help you eliminate the problem.
When trying to sort out the problem, I would be running either straight rain-water or distilled water. It is not going to cause any corrosion on the short time you are going to to troubleshoot and water has far better heat transfer properties than any other coolant. Also it is cheap and environmentally friendly to dump between eliminating different possible faults.
Bookmarks