Books have been written on this subject, to cover it here in a forum is not realistic. Before you do anything I recommend you do some basic head rebuilding searches.what other things should I best get done to the head? Ive no idea.
To cover things simply....(ill do my best.....) first... check all parts for damage. Any part that is damaged... check ALL the corresponding parts that went with it for damage... using your example of a burnt valve... check the valve seat and be prepared for a machine shop to install new ones.
I don't know 3SGTEs... but I have extensive expereince with 4AG... are you sure your pistons are not already forged?? Since you don't plan on extensive modifications, I'd use the OEM gasket for it seals better than any metal gasket will
Reshimming valves is done once you have the entire head rebuilt with new valves. You then adjust the valve clearence by check the gap between the cam lobe's bottom and the shim in the bucket. If your clearences are too much(too tight, or too loose) you'll reshim them till they are just right
I STRONGLY recommend a factory service manual for your 3SGTE... READ the overhaul sections... your understanding will grow with your increased knowledge.
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